Atomic Mass Chemistry Example 4

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Example 4

hard
An element has two isotopes. Isotope A has mass 10.01amu10.01\,\text{amu} and isotope B has mass 11.01amu11.01\,\text{amu}. The atomic mass listed on the periodic table is 10.81amu10.81\,\text{amu}. Calculate the percent abundance of each isotope.

Solution

  1. 1
    Let xx = fraction of isotope A. Then (1x)(1-x) = fraction of isotope B.
  2. 2
    Set up equation: 10.01x+11.01(1x)=10.8110.01x + 11.01(1-x) = 10.81. Simplify: 10.01x+11.0111.01x=10.8110.01x + 11.01 - 11.01x = 10.81.
  3. 3
    1.00x=0.20-1.00x = -0.20, so x=0.20x = 0.20. Isotope A: 20.0%20.0\%, Isotope B: 80.0%80.0\%. (This is boron: 10B{}^{10}\text{B} and 11B{}^{11}\text{B}.)

Answer

Isotope A: 20.0%,Isotope B: 80.0%\text{Isotope A: } 20.0\%,\quad \text{Isotope B: } 80.0\%
Working backward from the atomic mass to find isotope abundances requires setting up a system of equations. Since the atomic mass is closer to 11.01, isotope B must be more abundant.

About Atomic Mass

The weighted average mass of all naturally occurring isotopes of an element, expressed in atomic mass units (amu), where each isotope's mass is weighted by.

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