Atomic Mass Chemistry Example 2

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Example 2

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Silicon has three stable isotopes: 28Si{}^{28}\text{Si} (92.23%, mass 27.97727.977), 29Si{}^{29}\text{Si} (4.67%, mass 28.97628.976), and 30Si{}^{30}\text{Si} (3.10%, mass 29.974amu29.974\,\text{amu}). Calculate the atomic mass of silicon.

Solution

  1. 1
    Use the weighted average formula: mˉ=(mi×fi)\bar{m} = \sum (m_i \times f_i).
  2. 2
    mˉ=(27.977×0.9223)+(28.976×0.0467)+(29.974×0.0310)\bar{m} = (27.977 \times 0.9223) + (28.976 \times 0.0467) + (29.974 \times 0.0310).
  3. 3
    mˉ=25.803+1.353+0.929=28.09amu\bar{m} = 25.803 + 1.353 + 0.929 = 28.09\,\text{amu}.

Answer

Atomic mass of Si=28.09amu\text{Atomic mass of Si} = 28.09\,\text{amu}
This three-isotope calculation demonstrates the general method for computing atomic mass. The result is heavily weighted toward the most abundant isotope (28Si{}^{28}\text{Si} at 92.23%), which is why the atomic mass is close to 28.

About Atomic Mass

The weighted average mass of all naturally occurring isotopes of an element, expressed in atomic mass units (amu), where each isotope's mass is weighted by.

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