Atomic Mass Examples in Chemistry

Start with the recap, study the fully worked examples, then use the practice problems to check your understanding of Atomic Mass.

This page combines explanation, solved examples, and follow-up practice so you can move from recognition to confident problem-solving in Chemistry.

Concept Recap

The weighted average mass of all naturally occurring isotopes of an element, expressed in atomic mass units (amu), where each isotope's mass is weighted by its relative natural abundance.

The number under each element on the periodic table—a weighted average of all its isotopes.

Read the full concept explanation →

How to Use These Examples

  • Read the first worked example with the solution open so the structure is clear.
  • Try the practice problems before revealing each solution.
  • Use the related concepts and background knowledge badges if you feel stuck.

What to Focus On

Core idea: Atomic Mass starts with the given amount, names the substance, and chooses the conversion factor that cancels the old unit.

Common stuck point: Students often know a formula related to atomic mass but skip the recognition step: Am I using a mole bridge, molar mass, formula ratio, or balanced-equation ratio to connect measured amounts? That leads to a correct-looking substitution attached to the wrong chemical model.

Sense of Study hint: Ask: Am I using a mole bridge, molar mass, formula ratio, or balanced-equation ratio to connect measured amounts?

Worked Examples

Example 1

easy
Define atomic mass and explain why the atomic mass of carbon is listed as 12.01amu12.01\,\text{amu} rather than exactly 12amu12\,\text{amu} on the periodic table.

Answer

Atomic mass of C=12.01amu (weighted average of isotopes)\text{Atomic mass of C} = 12.01\,\text{amu (weighted average of isotopes)}

First step

1
Atomic mass is the weighted average of the masses of all naturally occurring isotopes of an element, measured in atomic mass units (amu).

Full solution

  1. 2
    Carbon has two stable isotopes: 12C{}^{12}\text{C} (mass 12, abundance 98.9%) and 13C{}^{13}\text{C} (mass 13, abundance 1.1%).
  2. 3
    Weighted average: 12×0.989+13×0.011=11.87+0.14=12.01amu12 \times 0.989 + 13 \times 0.011 = 11.87 + 0.14 = 12.01\,\text{amu}.
The atomic mass on the periodic table reflects the natural isotope distribution. Since 12C{}^{12}\text{C} is by far the most abundant isotope, the average is very close to 12 but slightly above due to the small contribution of 13C{}^{13}\text{C}.

Example 2

medium
Silicon has three stable isotopes: 28Si{}^{28}\text{Si} (92.23%, mass 27.97727.977), 29Si{}^{29}\text{Si} (4.67%, mass 28.97628.976), and 30Si{}^{30}\text{Si} (3.10%, mass 29.974amu29.974\,\text{amu}). Calculate the atomic mass of silicon.

Example 3

medium
An element has two isotopes: 40amu40\,\text{amu} at 80%80\% abundance and 42amu42\,\text{amu} at 20%20\%. Find the atomic mass.

Example 4

medium
Element X has two isotopes: 63amu63\,\text{amu} (x%x\%) and 65amu65\,\text{amu} (1x%1-x\%). The atomic mass is 63.55amu63.55\,\text{amu}. Find each percent abundance.

Example 5

hard
An element has three isotopes: 20amu20\,\text{amu} (90.48%90.48\%), 21amu21\,\text{amu} (0.27%0.27\%), 22amu22\,\text{amu} (9.25%9.25\%). Find atomic mass to two decimals.

Example 6

hard
An element has isotopes 185amu185\,\text{amu} (37.40%37.40\%) and 187amu187\,\text{amu} (62.60%62.60\%). Find atomic mass.

Practice Problems

Try these problems on your own first, then open the solution to compare your method.

Example 1

medium
Chlorine has two stable isotopes: 35Cl{}^{35}\text{Cl} (mass 34.97amu34.97\,\text{amu}, 75.77%) and 37Cl{}^{37}\text{Cl} (mass 36.97amu36.97\,\text{amu}, 24.23%). Calculate its atomic mass.

Example 2

hard
An element has two isotopes. Isotope A has mass 10.01amu10.01\,\text{amu} and isotope B has mass 11.01amu11.01\,\text{amu}. The atomic mass listed on the periodic table is 10.81amu10.81\,\text{amu}. Calculate the percent abundance of each isotope.

Example 3

medium
An element has isotopes 39 amu39\text{ amu} (93%93\%) and 41 amu41\text{ amu} (7%7\%). Find its atomic mass to two decimals.

Example 4

easy
An element has two isotopes: 50%50\% at 10 amu10\text{ amu} and 50%50\% at 12 amu12\text{ amu}. What is its atomic mass?

Example 5

easy
Is atomic mass a whole number or typically a decimal? Why for chlorine (35.5 amu35.5\text{ amu})?

Example 6

easy
What is the difference between atomic mass and mass number?

Example 7

easy
Element X has isotopes of 20 amu20\text{ amu} (75%75\%) and 22 amu22\text{ amu} (25%25\%). Set up the atomic-mass expression.

Example 8

easy
The atomic mass of carbon is 12.01 amu12.01\text{ amu}. Which isotope dominates its abundance?

Example 9

easy
Atomic number counts protons; what does atomic mass primarily reflect?

Example 10

easy
An element has one isotope only, at 19 amu19\text{ amu}. What is its atomic mass?

Example 11

easy
Why is the atomic mass used (not mass number) when computing molar mass for a real sample?

Example 12

medium
Element X has isotopes 24 amu24\text{ amu} (60%60\%) and 26 amu26\text{ amu} (40%40\%). Find its atomic mass.

Example 13

medium
Chlorine has ClCl-3535 (75%75\%) and ClCl-3737 (25%25\%). Compute the atomic mass.

Example 14

medium
An element has isotopes 63 amu63\text{ amu} (69%69\%) and 65 amu65\text{ amu} (31%31\%). Find the atomic mass to two decimals.

Example 15

medium
An element has isotopes 6 amu6\text{ amu} and 7 amu7\text{ amu}, with atomic mass 6.94 amu6.94\text{ amu}. Estimate the abundance of the 7 amu7\text{ amu} isotope.

Example 16

medium
An element has isotopes 10 amu10\text{ amu} (20%20\%) and 11 amu11\text{ amu} (80%80\%). Find the atomic mass.

Example 17

medium
Two isotopes have masses 84 amu84\text{ amu} and 86 amu86\text{ amu} in a 1:31:3 ratio. Find the atomic mass.

Example 18

medium
If a sample is 90%90\% of a 20 amu20\text{ amu} isotope and 10%10\% of a 22 amu22\text{ amu} isotope, what is the atomic mass?

Example 19

medium
An element's atomic mass is 24.3 amu24.3\text{ amu} with isotopes 2424, 2525, and 26 amu26\text{ amu}. If 2424 is 79%79\% and 2525 is 10%10\%, what is the 2626 abundance, and verify the mass.

Example 20

challenge
An element has isotopes 69 amu69\text{ amu} and 71 amu71\text{ amu} and an atomic mass of 69.7 amu69.7\text{ amu}. Find each isotope's percent abundance.

Example 21

challenge
A sample of element Z is enriched: isotope 235 amu235\text{ amu} raised to 4%4\% and isotope 238 amu238\text{ amu} at 96%96\%. Find the average atomic mass to two decimals.

Example 22

challenge
An element has isotopes 2828, 2929, 30 amu30\text{ amu} at 92%92\%, 5%5\%, 3%3\%. Compute the atomic mass to two decimals.

Example 23

easy
Is atomic mass the same for every atom of an element?

Example 24

easy
True or false: a single 12C^{12}\text{C} atom has a mass of exactly 12 amu by definition.

Example 25

easy
An element has a single isotope of mass 40 amu. What is the atomic mass?

Example 26

easy
What is the approximate atomic mass of hydrogen?

Example 27

easy
1 mole of an element has a mass in grams equal to what number?

Example 28

easy
Bromine's atomic mass is 79.9amu79.9\,\text{amu}. About what is the molar mass in g/mol?

Example 29

medium
An element has isotopes 54amu54\,\text{amu} (5.85%5.85\%), 56amu56\,\text{amu} (91.75%91.75\%), 57amu57\,\text{amu} (2.12%2.12\%), 58amu58\,\text{amu} (0.28%0.28\%). Find the atomic mass to two decimals.

Example 30

medium
How many grams are in 2.50mol2.50\,\text{mol} of an element whose atomic mass is 32.07amu32.07\,\text{amu}?

Example 31

medium
An element has isotopes 122amu122\,\text{amu} (57%57\%) and 124amu124\,\text{amu} (43%43\%). Find the atomic mass.

Example 32

medium
An element with atomic mass close to 24.31amu24.31\,\text{amu} has isotopes 2424, 2525, 26amu26\,\text{amu}. Which is the most abundant?

Example 33

medium
Magnesium's atomic mass is 24.31amu24.31\,\text{amu}. Estimate the mass of 0.500mol0.500\,\text{mol} of magnesium.

Example 34

medium
An element has isotopes 107amu107\,\text{amu} (51.84%51.84\%) and 109amu109\,\text{amu} (48.16%48.16\%). Find atomic mass.

Example 35

hard
How many moles are in 50.0g50.0\,\text{g} of an element with atomic mass 200.0amu200.0\,\text{amu}?

Example 36

hard
If iron's atomic mass is 55.85amu55.85\,\text{amu}, how many iron atoms are in 11.17g11.17\,\text{g} of iron?

Example 37

hard
An element has two isotopes 79amu79\,\text{amu} and 81amu81\,\text{amu}, atomic mass 79.90amu79.90\,\text{amu}. Find each abundance.

Example 38

hard
A sample is 100%100\% enriched to a single isotope of mass 235amu235\,\text{amu}. What is the atomic mass of this enriched sample?

Example 39

hard
What mass in grams contains 3.011×10233.011\times 10^{23} atoms of an element with atomic mass 40.08amu40.08\,\text{amu}?

Example 40

challenge
Atomic mass is 35.45amu35.45\,\text{amu} for chlorine with isotopes 3535 and 37amu37\,\text{amu}. Suppose a sample is enriched to 50%50\% of each. What is the new sample's atomic mass?

Example 41

challenge
A diatomic element has atomic mass 19.00amu19.00\,\text{amu}. What is the molar mass of the X2\text{X}_2 molecule?

Related Concepts

Background Knowledge

These ideas may be useful before you work through the harder examples.

isotope