Solubility Chemistry Example 4

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Example 4

hard
Explain why a scuba diver must ascend slowly, using the concept of gas solubility and Henry's Law. What happens to the dissolved nitrogen in the diver's blood as pressure decreases?

Solution

  1. 1
    Henry's Law states that gas solubility is directly proportional to the pressure of the gas above the liquid: C=kHƗPC = k_H \times P. At depth, high pressure increases nitrogen solubility in blood.
  2. 2
    If the diver ascends too quickly, the pressure drops rapidly, and dissolved nitrogen comes out of solution as bubbles in the bloodstream (decompression sickness or 'the bends').
  3. 3
    Ascending slowly allows nitrogen to gradually leave the blood through the lungs as pressure decreases, preventing dangerous bubble formation.

Answer

RapidĀ ascent → pressureĀ drop → N2Ā bubblesĀ inĀ bloodĀ (theĀ bends)\text{Rapid ascent → pressure drop → N}_2\text{ bubbles in blood (the bends)}
This is a life-threatening application of gas solubility principles. Henry's Law governs how gases dissolve under pressure, and decompression sickness demonstrates the consequences of violating these principles.

About Solubility

The maximum amount of a solute that can dissolve in a given quantity of solvent at a specific temperature and pressure, typically expressed as grams.

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