Double Displacement Chemistry Example 4

Follow the full solution, then compare it with the other examples linked below.

Example 4

hard
When solutions of lead(II) nitrate and potassium iodide are mixed, a bright yellow precipitate forms. Write the balanced molecular equation, identify the precipitate, and explain how to predict which product is insoluble.

Solution

  1. 1
    Reactants: Pb(NO3)2\text{Pb(NO}_3)_2 and KI\text{KI}. In double displacement, cations swap anions.
  2. 2
    Products: PbI2\text{PbI}_2 and KNO3\text{KNO}_3. Balanced: Pb(NO3)2+2KIโ†’PbI2โ†“+2KNO3\text{Pb(NO}_3)_2 + 2\text{KI} \rightarrow \text{PbI}_2\downarrow + 2\text{KNO}_3.
  3. 3
    The yellow precipitate is lead(II) iodide (PbI2\text{PbI}_2). Solubility rules: most iodides are soluble EXCEPT those of Pb2+\text{Pb}^{2+}, Ag+\text{Ag}^+, and Hg22+\text{Hg}_2^{2+}. All nitrates are soluble.

Answer

Pb(NO3)2+2KIโ†’PbI2โ†“+2KNO3\text{Pb(NO}_3)_2 + 2\text{KI} \rightarrow \text{PbI}_2\downarrow + 2\text{KNO}_3
Double displacement reactions in aqueous solution are driven by the formation of an insoluble precipitate, water, or a gas. Solubility rules let you predict whether a precipitate will form before mixing.

About Double Displacement

A double displacement (or metathesis) reaction occurs when two ionic compounds in solution exchange partners: AB + CD โ†’ AD + CB.

Learn more about Double Displacement โ†’

More Double Displacement Examples