Combustion Chemistry Example 4

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Example 4

hard
Ethanol (C2H5OH\text{C}_2\text{H}_5\text{OH}) is used as a fuel additive. Write the balanced equation for its complete combustion. If only limited oxygen is available, what products form instead (incomplete combustion)?

Solution

  1. 1
    Complete combustion: C2H5OH+3O2โ†’2CO2+3H2O\text{C}_2\text{H}_5\text{OH} + 3\text{O}_2 \rightarrow 2\text{CO}_2 + 3\text{H}_2\text{O}.
  2. 2
    Incomplete combustion (limited O2\text{O}_2): produces carbon monoxide (CO\text{CO}) or soot (carbon, C\text{C}) instead of CO2\text{CO}_2. Example: 2C2H5OH+4O2โ†’4CO+6H2O2\text{C}_2\text{H}_5\text{OH} + 4\text{O}_2 \rightarrow 4\text{CO} + 6\text{H}_2\text{O}.
  3. 3
    Incomplete combustion is dangerous because CO\text{CO} is colorless, odorless, and toxic.

Answer

C2H5OH+3O2โ†’2CO2+3H2O(complete)\text{C}_2\text{H}_5\text{OH} + 3\text{O}_2 \rightarrow 2\text{CO}_2 + 3\text{H}_2\text{O} \quad (\text{complete})
Complete combustion of any hydrocarbon or alcohol produces COโ‚‚ and Hโ‚‚O. Insufficient oxygen leads to incomplete combustion, producing CO or C โ€” this is why proper ventilation is critical for any fuel-burning appliance.

About Combustion

A rapid exothermic chemical reaction in which a fuel reacts with oxygen gas, releasing large amounts of energy as heat and light.

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