Practice Molecular Geometry in Chemistry

Use these practice problems to test your method after reviewing the concept explanation and worked examples.

Quick Recap

The three-dimensional arrangement of atoms in a molecule, predicted by Valence Shell Electron Pair Repulsion (VSEPR) theory, which states that electron pairs around a central atom arrange themselves as far apart as possible to minimize repulsion, determining the molecule's shape (e.g., linear, trigonal planar, tetrahedral, bent).

Electron pairs repel each other, pushing atoms as far apart as possible — this determines the molecule's shape.

Showing a random 20 of 50 problems.

Example 1

easy
What does the acronym VSEPR stand for?

Example 2

medium
What is the molecular geometry of PCl5PCl_5 (5 bonds, no lone pairs)?

Example 3

medium
What is the molecular geometry of OF2OF_2 (O has 2 bonds, 2 lone pairs)?

Example 4

medium
Determine the molecular geometry of CO2CO_2 (C has 2 double bonds, no lone pairs).

Example 5

easy
What is the ideal bond angle for trigonal planar geometry?

Example 6

medium
Why is CO2CO_2 nonpolar but SO2SO_2 polar?

Example 7

medium
Distinguish electron geometry from molecular geometry for NH3NH_3.

Example 8

hard
Predict the molecular geometry of BrF5BrF_5.

Example 9

medium
What is the molecular geometry of PH3PH_3?

Example 10

easy
How many bonding regions does a tetrahedral molecule (no lone pairs) have?

Example 11

hard
Explain why lone pairs in a trigonal bipyramidal geometry occupy equatorial rather than axial positions.

Example 12

medium
What is the molecular geometry of H2SH_2S (S has 2 bonds and 2 lone pairs)?

Example 13

medium
Predict the molecular geometry of I3I_3^-.

Example 14

medium
Predict the molecular geometry of CCl4CCl_4.

Example 15

easy
How many electron domains does a central atom in a linear molecule (no lone pairs) have?

Example 16

medium
For SO3SO_3, predict the geometry and bond angle.

Example 17

easy
How many electron domains surround the central atom in a trigonal planar molecule?

Example 18

easy
What is the molecular geometry of BeCl2BeCl_2 (Be has 2 bonds, no lone pairs)?

Example 19

challenge
NH3NH_3 has bond angle ~107° and NF3NF_3 has ~102°. Both are trigonal pyramidal — explain the difference.

Example 20

challenge
Predict the molecular geometry of SF4SF_4 (S has 4 bonds and 1 lone pair).