Excess Reactant Examples in Chemistry

Start with the recap, study the fully worked examples, then use the practice problems to check your understanding of Excess Reactant.

This page combines explanation, solved examples, and follow-up practice so you can move from recognition to confident problem-solving in Chemistry.

Concept Recap

The reactant that remains after a reaction stops because the limiting reactant has been used up.

If one ingredient runs out first, the other one is left over.

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How to Use These Examples

  • Read the first worked example with the solution open so the structure is clear.
  • Try the practice problems before revealing each solution.
  • Use the related concepts and background knowledge badges if you feel stuck.

What to Focus On

Core idea: Excess Reactant starts with the given amount, names the substance, and chooses the conversion factor that cancels the old unit.

Common stuck point: Students often know a formula related to excess reactant but skip the recognition step: Am I using a mole bridge, molar mass, formula ratio, or balanced-equation ratio to connect measured amounts? That leads to a correct-looking substitution attached to the wrong chemical model.

Sense of Study hint: Ask: Am I using a mole bridge, molar mass, formula ratio, or balanced-equation ratio to connect measured amounts?

Worked Examples

Example 1

easy
In Mg+2HClMgCl2+H2Mg + 2HCl \rightarrow MgCl_2 + H_2, 2 mol2\text{ mol} MgMg and 5 mol5\text{ mol} HClHCl react. Identify the excess reactant.

Answer

MgMg

First step

1
2 mol2\text{ mol} MgMg requires 2×2=4 mol2 \times 2 = 4\text{ mol} HClHCl.

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Example 2

medium
In 2Ag+Cl22AgCl2Ag + Cl_2 \rightarrow 2AgCl, 0.4 mol0.4\text{ mol} AgAg and 0.3 mol0.3\text{ mol} Cl2Cl_2 react. Find the moles of excess reactant remaining.

Example 3

medium
In 2NaOH+H2SO4Na2SO4+2H2O2NaOH + H_2SO_4 \rightarrow Na_2SO_4 + 2H_2O, 0.6 mol0.6\text{ mol} NaOHNaOH and 0.4 mol0.4\text{ mol} H2SO4H_2SO_4 react. Find the excess reactant remaining.

Example 4

medium
In 2KMnO4+16HCl2KCl+2MnCl2+5Cl2+8H2O2KMnO_4 + 16HCl \rightarrow 2KCl + 2MnCl_2 + 5Cl_2 + 8H_2O, 0.2 mol0.2\text{ mol} KMnO4KMnO_4 and 2 mol2\text{ mol} HClHCl react. How many moles of HClHCl remain?

Example 5

hard
In 2AgNO3+CaCl22AgCl+Ca(NO3)22AgNO_3 + CaCl_2 \rightarrow 2AgCl + Ca(NO_3)_2, 0.6 mol0.6\text{ mol} AgNO3AgNO_3 and 0.4 mol0.4\text{ mol} CaCl2CaCl_2 react. Find excess reactant remaining.

Example 6

hard
In 4Fe+3O22Fe2O34Fe + 3O_2 \rightarrow 2Fe_2O_3, 11.2 g11.2\text{ g} FeFe (M=56M=56) and 4.8 g4.8\text{ g} O2O_2 (M=32M=32) react. How many grams of excess reactant remain?

Example 7

challenge
In 2KClO32KCl+3O22KClO_3 \rightarrow 2KCl + 3O_2 ... since decomposition has only one reactant, instead consider 3Mg+N2Mg3N23Mg + N_2 \rightarrow Mg_3N_2. If 0.9 mol0.9\text{ mol} MgMg and 0.4 mol0.4\text{ mol} N2N_2 react, find excess remaining and moles of Mg3N2Mg_3N_2 formed.

Practice Problems

Try these problems on your own first, then open the solution to compare your method.

Example 1

medium
In 2H2+O22H2O2H_2 + O_2 \rightarrow 2H_2O, 5 mol5\text{ mol} H2H_2 and 4 mol4\text{ mol} O2O_2 react. How many moles of excess reactant remain?

Example 2

easy
In a reaction, AA is the limiting reactant and BB is left over after the reaction stops. Which is the excess reactant?

Example 3

easy
If 5 mol5\text{ mol} of a reactant is provided but only 3 mol3\text{ mol} is consumed, how much is in excess?

Example 4

easy
In 2H2+O22H2O2H_2 + O_2 \rightarrow 2H_2O, you have 2 mol2\text{ mol} H2H_2 and 2 mol2\text{ mol} O2O_2. Which is in excess?

Example 5

easy
After a reaction, 0.8 mol0.8\text{ mol} of a reactant remains unreacted. What is this leftover called?

Example 6

easy
In N2+3H22NH3N_2 + 3H_2 \rightarrow 2NH_3, 1 mol1\text{ mol} N2N_2 reacts with 3 mol3\text{ mol} H2H_2. With 1 mol1\text{ mol} N2N_2 and 5 mol5\text{ mol} H2H_2, which is excess?

Example 7

easy
You supply 10 g10\text{ g} of a reactant and 4 g4\text{ g} reacts. What mass is in excess?

Example 8

easy
Does the excess reactant or the limiting reactant determine how much product forms?

Example 9

easy
In a 1:11:1 reaction A+BCA + B \rightarrow C, you have 4 mol4\text{ mol} AA and 6 mol6\text{ mol} BB. Which is excess and by how much?

Example 10

medium
In 2Na+Cl22NaCl2Na + Cl_2 \rightarrow 2NaCl, you mix 4 mol4\text{ mol} NaNa with 3 mol3\text{ mol} Cl2Cl_2. Which is excess and how much remains?

Example 11

medium
In C+O2CO2C + O_2 \rightarrow CO_2, 24 g24\text{ g} carbon reacts with 64 g64\text{ g} oxygen. Which is excess? (C=12C=12, O2=32 g/molO_2=32\text{ g/mol})

Example 12

medium
In 2H2+O22H2O2H_2 + O_2 \rightarrow 2H_2O, 6 mol6\text{ mol} H2H_2 and 2 mol2\text{ mol} O2O_2 react. How many moles of the excess reactant remain?

Example 13

medium
In N2+3H22NH3N_2 + 3H_2 \rightarrow 2NH_3, 2 mol2\text{ mol} N2N_2 and 9 mol9\text{ mol} H2H_2 react. How much excess reactant remains?

Example 14

medium
In CH4+2O2CO2+2H2OCH_4 + 2O_2 \rightarrow CO_2 + 2H_2O, 3 mol3\text{ mol} CH4CH_4 and 4 mol4\text{ mol} O2O_2 react. Which is excess and how much remains?

Example 15

medium
In A+2BCA + 2B \rightarrow C, you have 5 mol5\text{ mol} AA and 8 mol8\text{ mol} BB. How much of the excess reactant remains?

Example 16

medium
In 2Al+3Cl22AlCl32Al + 3Cl_2 \rightarrow 2AlCl_3, 4 mol4\text{ mol} AlAl and 9 mol9\text{ mol} Cl2Cl_2 react. How many moles of excess reactant remain?

Example 17

medium
In A+BCA + B \rightarrow C (1:11:1), 30 g30\text{ g} AA (M=30 g/molM=30\text{ g/mol}) and 50 g50\text{ g} BB (M=25 g/molM=25\text{ g/mol}) react. Mass of excess BB remaining?

Example 18

challenge
In 2H2+O22H2O2H_2 + O_2 \rightarrow 2H_2O, 8 g8\text{ g} H2H_2 (M=2M=2) and 96 g96\text{ g} O2O_2 (M=32M=32) react. How many grams of excess reactant remain?

Example 19

challenge
In N2+3H22NH3N_2 + 3H_2 \rightarrow 2NH_3, after reacting 1 mol1\text{ mol} N2N_2 with 4 mol4\text{ mol} H2H_2, how many total moles of gas (excess + product) are present at completion?

Example 20

challenge
In A+3B2CA + 3B \rightarrow 2C, mixing xx mol AA with 7 mol7\text{ mol} BB leaves 1 mol1\text{ mol} BB in excess. Find xx (assume AA is limiting).

Example 21

easy
In A+BCA + B \rightarrow C (1:1), 3 mol3\text{ mol} AA and 7 mol7\text{ mol} BB react. Which is the excess reactant?

Example 22

easy
In Zn+2HClZnCl2+H2Zn + 2HCl \rightarrow ZnCl_2 + H_2, 1 mol1\text{ mol} ZnZn reacts with 3 mol3\text{ mol} HClHCl. Which is in excess?

Example 23

easy
A reaction needs reactants in a 1:21:2 ratio. You mix 2 mol2\text{ mol} of each. Which is in excess?

Example 24

medium
In 2Mg+O22MgO2Mg + O_2 \rightarrow 2MgO, 6 mol6\text{ mol} MgMg reacts with 4 mol4\text{ mol} O2O_2. How many moles of the excess reactant remain after the reaction?

Example 25

medium
In 2KClO32KCl+3O22KClO_3 \rightarrow 2KCl + 3O_2 ... this is a decomposition, no excess possible. Instead, for Fe+SFeSFe + S \rightarrow FeS (1:1), 5 mol5\text{ mol} FeFe and 3 mol3\text{ mol} SS react. Excess remaining?

Example 26

medium
In 3Fe+2O2Fe3O43Fe + 2O_2 \rightarrow Fe_3O_4, 9 mol9\text{ mol} FeFe reacts with 8 mol8\text{ mol} O2O_2. How many moles of excess reactant remain?

Example 27

medium
In CaCO3+2HClCaCl2+CO2+H2OCaCO_3 + 2HCl \rightarrow CaCl_2 + CO_2 + H_2O, 2 mol2\text{ mol} CaCO3CaCO_3 and 3 mol3\text{ mol} HClHCl react. How many moles of excess reactant remain?

Example 28

medium
In 4Fe+3O22Fe2O34Fe + 3O_2 \rightarrow 2Fe_2O_3, 8 mol8\text{ mol} FeFe and 9 mol9\text{ mol} O2O_2 react. Which is the excess reactant and by how much?

Example 29

medium
In S+O2SO2S + O_2 \rightarrow SO_2, 32 g32\text{ g} SS (M=32M=32) and 64 g64\text{ g} O2O_2 (M=32M=32) react. How many grams of excess reactant remain?

Example 30

medium
In 2H2+O22H2O2H_2 + O_2 \rightarrow 2H_2O, 10 mol10\text{ mol} H2H_2 and 4 mol4\text{ mol} O2O_2 react. How many moles of H2H_2 remain at completion?

Example 31

medium
In 2C+O22CO2C + O_2 \rightarrow 2CO, 6 mol6\text{ mol} CC and 4 mol4\text{ mol} O2O_2 react. How many moles of excess reactant remain?

Example 32

medium
In Cu+2AgNO3Cu(NO3)2+2AgCu + 2AgNO_3 \rightarrow Cu(NO_3)_2 + 2Ag, 0.5 mol0.5\text{ mol} CuCu and 0.8 mol0.8\text{ mol} AgNO3AgNO_3 react. Which is excess and how much remains?

Example 33

hard
In 4NH3+5O24NO+6H2O4NH_3 + 5O_2 \rightarrow 4NO + 6H_2O, 20 g20\text{ g} NH3NH_3 (M=17M=17) and 40 g40\text{ g} O2O_2 (M=32M=32) react. How many grams of excess reactant remain?

Example 34

hard
In N2+3H22NH3N_2 + 3H_2 \rightarrow 2NH_3, 14 g14\text{ g} N2N_2 (M=28M=28) and 6 g6\text{ g} H2H_2 (M=2M=2) react. How many grams of excess reactant remain?

Example 35

hard
In C3H8+5O23CO2+4H2OC_3H_8 + 5O_2 \rightarrow 3CO_2 + 4H_2O, 2 mol2\text{ mol} C3H8C_3H_8 and 8 mol8\text{ mol} O2O_2 react. How many moles of excess reactant remain?

Example 36

hard
In 2Al+6HCl2AlCl3+3H22Al + 6HCl \rightarrow 2AlCl_3 + 3H_2, 5.4 g5.4\text{ g} AlAl (M=27M=27) and 0.5 mol0.5\text{ mol} HClHCl react. Find moles of excess reactant remaining.

Example 37

hard
In 2H2+O22H2O2H_2 + O_2 \rightarrow 2H_2O, after combustion you find 0.8 mol0.8\text{ mol} of one reactant left and 0.6 mol0.6\text{ mol} H2OH_2O produced. Identify the excess reactant and the original amount supplied.

Example 38

hard
In CH4+2O2CO2+2H2OCH_4 + 2O_2 \rightarrow CO_2 + 2H_2O, 16 g16\text{ g} CH4CH_4 (M=16M=16) and 48 g48\text{ g} O2O_2 (M=32M=32) react. How many grams of excess reactant remain?

Example 39

challenge
A mixture of 0.3 mol0.3\text{ mol} H2H_2 and 0.3 mol0.3\text{ mol} O2O_2 is sparked. Reaction: 2H2+O22H2O2H_2 + O_2 \rightarrow 2H_2O. After reaction, total moles of gas (assuming water is liquid)?

Background Knowledge

These ideas may be useful before you work through the harder examples.

limiting reactant