Read the first worked example with the solution open so the structure is clear.
Try the practice problems before revealing each solution.
Use the related concepts and background knowledge badges if you feel stuck.
What to Focus On
Core idea:Electron Shell starts by naming the element, charge, and relevant protons, neutrons, or electrons.
Common stuck point:Students often know a formula related to electron shell but skip the recognition step: Am I using particle counts, nuclear charge, mass number, electron arrangement, or isotope notation to describe an atom or ion? That leads to a correct-looking substitution attached to the wrong chemical model.
Sense of Study hint:Ask: Am I using particle counts, nuclear charge, mass number, electron arrangement, or isotope notation to describe an atom or ion?
Worked Examples
Example 1
easy
How many electrons can each of the first three electron shells hold? Show the maximum capacity for shells n=1, n=2, and n=3.
Answer
n=1:2,n=2:8,n=3:18
First step
1
The maximum number of electrons in a shell is given by 2n2 where n is the shell number.
Electron shells are energy levels surrounding the nucleus. Inner shells are lower in energy and fill first. The formula 2n2 determines the capacity of each shell and explains why the periodic table has rows of different lengths.
Example 2
medium
Draw the electron shell diagram (Bohr model) for a sodium atom (Z=11). How many electrons are in each shell?Na: 2, 8, 1 — one valence electron in the outermost shell
Example 3
medium
Draw the electron shell diagram for sodium (Na, Z=11). How many electrons are in each shell?Na electron shell arrangement: 2, 8, 1
Example 4
medium
Why does the third shell appear to hold only 8 electrons in the configuration of argon (Z=18) even though 2n2=18?
Example 5
medium
Compare the outer-shell configurations of lithium (Z=3), sodium (Z=11), and potassium (Z=19). Why are their chemistries similar?
Example 6
hard
An ion has configuration 2,8,8 and a +1 charge. Identify the element it came from.
Practice Problems
Try these problems on your own first, then open the solution to compare your method.
Example 1
medium
Determine the electron shell arrangement for chlorine (Z=17). How many electrons are in the outermost shell, and what does this predict about chlorine's chemical behavior?Cl: 2, 8, 7 — 7 valence electrons, one short of a full octet
Example 2
hard
Compare the electron shell arrangements of neon (Z=10) and argon (Z=18). Explain why both are chemically inert despite having different numbers of total electrons.
Example 3
easy
What is an electron shell?
Example 4
easy
What is the maximum number of electrons the first shell (n=1) can hold?
Example 5
easy
Using 2n2, how many electrons fit in the second shell (n=2)?
Example 6
easy
Which shell fills first as electrons are added to an atom?
Example 7
easy
How many electrons does a neutral neon atom (10 electrons) place in its shells?Ne: 2, 8 — both shells completely filled
Example 8
easy
How many electrons are in the outer shell of a neutral oxygen atom (8 electrons)?
Example 9
easy
Electrons in shells follow fixed planetary orbits — true or false?
Example 10
easy
Why do electrons occupy the lowest available shell first?
Example 11
medium
A neutral sodium atom has 11 electrons. Write its electron-shell configuration.Na: 2, 8, 1
Example 12
medium
Using 2n2, how many electrons can the third shell (n=3) hold at maximum?
Example 13
medium
A neutral chlorine atom has 17 electrons. Give its shell configuration and the outer-shell count.Cl: 2, 8, 7 — outer shell has 7 electrons
Example 14
medium
Why do sodium (2, 8, 1) and lithium (2, 1) have similar chemistry?
Example 15
medium
Distinguish a shell from a subshell using the n=2 shell as an example.
Example 16
medium
A neutral atom has the configuration 2, 8, 8. How many electrons does it have and what element is it?
Example 17
medium
How many electrons does a neutral magnesium atom (12 electrons) have in its outermost shell?Mg: 2, 8, 2 — 2 electrons in the outermost shell
Example 18
medium
A neutral fluorine atom has 9 electrons. Write its electron-shell configuration and outer-shell count.F: 2, 7 — 7 electrons in the outer shell
Example 19
medium
How many electrons can the fourth shell (n=4) hold using 2n2?
Example 20
challenge
Potassium has 19 electrons. Its configuration is 2, 8, 8, 1 rather than 2, 8, 9. Explain why the fourth shell starts before the third is full.
Example 21
challenge
A neutral atom has 2 full shells and 4 electrons in its third shell. Find its atomic number and element.
Example 22
challenge
Why do noble gases like neon (2, 8) and argon (2, 8, 8) rarely react?
Example 23
easy
Using 2n2, find the maximum capacity of shell n=5.
Example 24
easy
How many electrons fit in the first three shells combined (n=1,2,3)?
Example 25
easy
What is the electron-shell configuration of a neutral aluminum atom (Z=13)?Al: 2, 8, 3
Example 26
easy
Write the shell configuration of a neutral silicon atom (Z=14).Si: 2, 8, 4
Example 27
easy
How many electrons does a neutral beryllium atom (4 electrons) have in its outermost shell?
Example 28
medium
A neutral sulfur atom has Z=16. Give its shell configuration and outermost electron count.S: 2, 8, 6 — 6 electrons in the outer shell
Example 29
medium
A neutral calcium atom has Z=20. Give its electron-shell configuration.Ca: 2, 8, 8, 2 — 4s fills before 3d
Example 30
medium
How many valence electrons does carbon (Z=6) have?
Example 31
medium
Which element has the configuration 2,8,5?
Example 32
medium
A neutral atom has configuration 2,8,18,1. Identify it.
Example 33
medium
How many electrons does a neutral nitrogen atom (Z=7) have in its outer shell?
Example 34
medium
How many electrons does a Mg2+ ion have, and what is its shell configuration?Mg²⁺: 10 electrons, configuration 2, 8
Example 35
medium
How many electrons does O2− have, and what is its shell configuration?O²⁻: 10 electrons, configuration 2, 8 (isoelectronic with Ne)
Example 36
hard
Write the shell configuration of a neutral bromine atom (Z=35).
Example 37
hard
What is the shell configuration of a neutral iron atom (Z=26)?
Example 38
hard
Why does adding a third shell to sodium (config 2,8,1) lower its ionization energy compared to lithium (2,1)?
Example 39
challenge
A particle has 17 protons and 18 electrons. Give its shell configuration, identity, and net charge.
Example 40
challenge
An emission line forms when an electron drops from n=3 to n=2 in hydrogen. Is the photon emitted in this transition higher or lower energy than one from n=4 to n=2?