The minimum kinetic energy that reactant particles must possess upon collision in order to break existing bonds and initiate a chemical reaction, represented as the energy barrier Ea between reactants and products.
The 'hill' reactants must climb over before the reaction can proceed.
Showing a random 20 of 50 problems.
Example 1
medium
An endothermic reaction has ΔH=+40kJ/mol and reverse Ea=25kJ/mol. Find the forward Ea.
Example 2
easy
Does a catalyst raise or lower the activation energy?
Example 3
medium
On an energy diagram, Reaction A has Ea=50kJ/mol and Reaction B has Ea=120kJ/mol. Both occur at the same temperature. Which reaction is faster and why?
Example 4
easy
A spark ignites a fuel-air mixture. What is the spark providing?
Example 5
challenge
A reaction has A=5.0×1012s−1 and Ea=90kJ/mol. Estimate k at 400K. Use R=8.314J/(mol⋅K).
Example 6
medium
Why does milk spoil more slowly when refrigerated?
Example 7
easy
Name the high-energy intermediate at the top of an energy diagram peak.
Example 8
medium
A reaction has Ea=65 kJ and ΔH=+25 kJ (endothermic). Are the products above or below the reactants, and by how much?
Example 9
easy
Does a catalyst change the activation energy of a reaction? How?
Example 10
medium
How does activation energy explain why food spoils faster at room temperature than in a fridge?
Example 11
medium
Hydrogen and oxygen can coexist at room temperature without reacting. Why?
Example 12
easy
Explain why a match must be struck before it ignites, even though combustion is exothermic.
Example 13
hard
Using the two-point Arrhenius form, if k doubles when T rises from 300K to 310K, estimate Ea. Use R=8.314J/(mol⋅K).
Example 14
easy
Why must reactant particles collide with at least the activation energy to react?
Example 15
easy
Do exothermic reactions have an activation energy?
Example 16
easy
What units are typically used to express activation energy?
Example 17
hard
Reaction A: Ea=50, ΔH=−10. Reaction B: Ea=50, ΔH=−60. Compare forward rates (assume similar A factors).
Example 18
easy
What is activation energy?
Example 19
easy
Is activation energy the same as the overall energy change ΔH?
Example 20
hard
Enzyme catalase lowers Ea for H2O2 decomposition from 75 to 8kJ/mol. By approximately what factor does k increase at 310K? Use RT≈2.58kJ/mol.