Redox Reaction Examples in Chemistry

Start with the recap, study the fully worked examples, then use the practice problems to check your understanding of Redox Reaction.

This page combines explanation, solved examples, and follow-up practice so you can move from recognition to confident problem-solving in Chemistry.

Concept Recap

A chemical reaction in which electrons are transferred from one substance (the reducing agent, which is oxidized) to another (the oxidizing agent, which is reduced).

One thing loses electrons (oxidized), another gains them (reduced).

Read the full concept explanation β†’

How to Use These Examples

  • Read the first worked example with the solution open so the structure is clear.
  • Try the practice problems before revealing each solution.
  • Use the related concepts and background knowledge badges if you feel stuck.

What to Focus On

Core idea: Redox Reaction starts by assigning oxidation and reduction, then traces electrons through the wire and ions through solution.

Common stuck point: Students often know a formula related to redox reaction but skip the recognition step: Am I tracking oxidation, reduction, electron flow, ions, electrodes, and whether the cell is spontaneous or driven? That leads to a correct-looking substitution attached to the wrong chemical model.

Sense of Study hint: Ask: Am I tracking oxidation, reduction, electron flow, ions, electrodes, and whether the cell is spontaneous or driven?

Worked Examples

Example 1

easy
Define a redox reaction and explain the relationship between oxidation and reduction.

Answer

Redox:Β electronΒ transfer.Β OxidationΒ =Β loss,Β ReductionΒ =Β gain.\text{Redox: electron transfer. Oxidation = loss, Reduction = gain.}

First step

1
A redox (reduction-oxidation) reaction involves the transfer of electrons between species.

Full solution

  1. 2
    Oxidation is the loss of electrons (increase in oxidation number). Reduction is the gain of electrons (decrease in oxidation number).
  2. 3
    Oxidation and reduction always occur together β€” one species cannot lose electrons unless another gains them. Remember: OIL RIG (Oxidation Is Loss, Reduction Is Gain).
Redox reactions are one of the most important classes of chemical reactions. They include combustion, corrosion, photosynthesis, respiration, and all electrochemical processes (batteries, electrolysis).

Example 2

medium
In the reaction Zn(s)+CuSO4(aq)β†’ZnSO4(aq)+Cu(s)\text{Zn(s)} + \text{CuSO}_4\text{(aq)} \rightarrow \text{ZnSO}_4\text{(aq)} + \text{Cu(s)}, identify the oxidizing agent and the reducing agent.

Example 3

medium
Determine if AgNO3+NaCl→AgCl+NaNO3\text{AgNO}_3 + \text{NaCl} \rightarrow \text{AgCl} + \text{NaNO}_3 is a redox reaction.

Example 4

medium
In a galvanic cell with Zn(s)/Zn2+^{2+} and Ag+^+/Ag(s), write the overall balanced redox equation.

Example 5

medium
Balance in acidic solution: Cr2O72βˆ’+Fe2+β†’Cr3++Fe3+\text{Cr}_2\text{O}_7^{2-} + \text{Fe}^{2+} \rightarrow \text{Cr}^{3+} + \text{Fe}^{3+}.

Practice Problems

Try these problems on your own first, then open the solution to compare your method.

Example 1

medium
Determine whether the following reaction is a redox reaction: HCl(aq)+NaOH(aq)β†’NaCl(aq)+H2O(l)\text{HCl(aq)} + \text{NaOH(aq)} \rightarrow \text{NaCl(aq)} + \text{H}_2\text{O(l)}. Justify your answer.

Example 2

hard
Balance the following redox reaction in acidic solution using the half-reaction method: MnO4βˆ’+Fe2+β†’Mn2++Fe3+\text{MnO}_4^- + \text{Fe}^{2+} \rightarrow \text{Mn}^{2+} + \text{Fe}^{3+}.

Example 3

easy
In the reaction Zn+Cu2+β†’Zn2++CuZn + Cu^{2+} \rightarrow Zn^{2+} + Cu, which species is oxidized?

Example 4

easy
What is the oxidation number of oxygen in most compounds such as H2OH_2O?

Example 5

easy
In 2H2+O2β†’2H2O2H_2 + O_2 \rightarrow 2H_2O, is this a redox reaction?

Example 6

easy
Define a reducing agent.

Example 7

easy
In Cu2++2eβˆ’β†’CuCu^{2+} + 2e^- \rightarrow Cu, is copper oxidized or reduced?

Example 8

easy
What is the oxidation number of a free element such as NaNa metal?

Example 9

easy
In a redox reaction, the oxidizing agent is the species that does what to electrons?

Example 10

easy
Find the oxidation number of SS in SO42βˆ’SO_4^{2-}.

Example 11

medium
Balance the oxidation half-reaction for iron going from Fe2+Fe^{2+} to Fe3+Fe^{3+}.

Example 12

medium
How many electrons are transferred when Alβ†’Al3+Al \rightarrow Al^{3+} is balanced with Cl2β†’2Clβˆ’Cl_2 \rightarrow 2Cl^- to form AlCl3AlCl_3?

Example 13

medium
In MnO4βˆ’β†’Mn2+MnO_4^- \rightarrow Mn^{2+}, what is the change in oxidation number of Mn?

Example 14

medium
Identify the oxidizing agent in Zn+2HCl→ZnCl2+H2Zn + 2HCl \rightarrow ZnCl_2 + H_2.

Example 15

medium
Balance the reduction half-reaction O2β†’O2βˆ’O_2 \rightarrow O^{2-} for the oxide ion.

Example 16

medium
In 2Fe3++Sn2+β†’2Fe2++Sn4+2Fe^{3+} + Sn^{2+} \rightarrow 2Fe^{2+} + Sn^{4+}, how many electrons does tin lose?

Example 17

medium
Is the disproportionation Cl2β†’Clβˆ’+ClOβˆ’Cl_2 \rightarrow Cl^- + ClO^- a redox reaction?

Example 18

medium
What is the oxidation number of nitrogen in HNO3HNO_3?

Example 19

medium
Assign the oxidation number of carbon in CH4CH_4 (methane).

Example 20

challenge
Balance the redox equation in acidic solution: MnO4βˆ’+Fe2+β†’Mn2++Fe3+MnO_4^- + Fe^{2+} \rightarrow Mn^{2+} + Fe^{3+}.

Example 21

challenge
A galvanic cell uses Zn∣Zn2+Zn|Zn^{2+} and Cu2+∣CuCu^{2+}|Cu. Write the balanced overall redox and name the species reduced.

Example 22

challenge
In 3Cu+8HNO3β†’3Cu(NO3)2+2NO+4H2O3Cu + 8HNO_3 \rightarrow 3Cu(NO_3)_2 + 2NO + 4H_2O, how many electrons are transferred total?

Example 23

easy
In 2Mg+O2β†’2MgO2\text{Mg} + \text{O}_2 \rightarrow 2\text{MgO}, which element is oxidized?

Example 24

easy
What is the oxidation number of H in HCl?

Example 25

easy
In 2Na+Cl2β†’2NaCl2\text{Na} + \text{Cl}_2 \rightarrow 2\text{NaCl}, which species is the reducing agent?

Example 26

easy
In Cl2+2eβˆ’β†’2Clβˆ’\text{Cl}_2 + 2e^- \rightarrow 2\text{Cl}^-, is chlorine oxidized or reduced?

Example 27

medium
Find the oxidation number of Cr in Cr2O72βˆ’\text{Cr}_2\text{O}_7^{2-}.

Example 28

medium
In Sn2+β†’Sn4++2eβˆ’\text{Sn}^{2+} \rightarrow \text{Sn}^{4+} + 2e^-, is this oxidation or reduction?

Example 29

medium
In CuO+H2β†’Cu+H2O\text{CuO} + \text{H}_2 \rightarrow \text{Cu} + \text{H}_2\text{O}, what is the reducing agent?

Example 30

medium
Find the oxidation number of N in NH4+\text{NH}_4^+.

Example 31

medium
In Cu+2Ag+β†’Cu2++2Ag\text{Cu} + 2\text{Ag}^+ \rightarrow \text{Cu}^{2+} + 2\text{Ag}, how many electrons are transferred per Cu atom?

Example 32

medium
In the combustion of methane CH4+2O2β†’CO2+2H2O\text{CH}_4 + 2\text{O}_2 \rightarrow \text{CO}_2 + 2\text{H}_2\text{O}, what is the oxidation state change of carbon?

Example 33

medium
At which electrode does oxidation occur in a galvanic cell?

Example 34

medium
Is CaCO3β†’CaO+CO2\text{CaCO}_3 \rightarrow \text{CaO} + \text{CO}_2 a redox reaction?

Example 35

medium
Find the oxidation state of Mn in KMnO4\text{KMnO}_4.

Example 36

hard
Balance in basic solution: MnO4βˆ’+Iβˆ’β†’MnO2+I2\text{MnO}_4^- + \text{I}^- \rightarrow \text{MnO}_2 + \text{I}_2.

Example 37

hard
In the disproportionation 2H2O2β†’2H2O+O22\text{H}_2\text{O}_2 \rightarrow 2\text{H}_2\text{O} + \text{O}_2, what oxidation states does O take on each side?

Example 38

hard
How many moles of electrons are transferred when 11 mol Al is oxidized to Al3+^{3+}?

Example 39

hard
In NaH\text{NaH}, what is the oxidation state of hydrogen?

Example 40

hard
In 3NO2+H2O→2HNO3+NO3\text{NO}_2 + \text{H}_2\text{O} \rightarrow 2\text{HNO}_3 + \text{NO}, identify N's oxidation states and label the disproportionation.

Example 41

hard
In a galvanic cell with overall reaction Zn+Cu2+β†’Zn2++Cu\text{Zn} + \text{Cu}^{2+} \rightarrow \text{Zn}^{2+} + \text{Cu}, identify the species reduced and the cathode material.

Example 42

challenge
For 5H2O2+2MnO4βˆ’+6H+β†’2Mn2++5O2+8H2O5\text{H}_2\text{O}_2 + 2\text{MnO}_4^- + 6\text{H}^+ \rightarrow 2\text{Mn}^{2+} + 5\text{O}_2 + 8\text{H}_2\text{O}, how many electrons are transferred per formula unit of MnO4βˆ’_4^- reduced?

Background Knowledge

These ideas may be useful before you work through the harder examples.

oxidationreduction