Lewis Structure Chemistry Example 2

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Example 2

medium
Draw the Lewis structure for carbon dioxide (CO2\text{CO}_2).

Solution

  1. 1
    Count total valence electrons: C has 4, each O has 6. Total = 4+2(6)=164 + 2(6) = 16.
  2. 2
    Place C as central atom. With single bonds to each O: O–C–O\text{O–C–O} uses 4 electrons, leaving 12.
  3. 3
    Place remaining electrons on O atoms (3 lone pairs each = 12 electrons). But C only has 4 electrons — it needs 8.
  4. 4
    Move lone pairs to form double bonds: O=C=O\text{O=C=O}. Now C has 8 electrons (two double bonds), each O has 8 (2 bonding + 2 lone pairs).

Answer

O=C=O (each O has 2 lone pairs)\text{O=C=O (each O has 2 lone pairs)}
When single bonds don't give every atom an octet, lone pairs must be converted into bonding pairs (double or triple bonds). CO2_2 is a linear molecule with two double bonds.

About Lewis Structure

A two-dimensional diagram that represents the arrangement of valence electrons around atoms in a molecule, showing bonding pairs as lines between atoms and non-bonding (lone).

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