Formula Writing Chemistry Example 2

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Example 2

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Write the chemical formula for calcium phosphate using the crisscross method. Calcium forms Ca2+\text{Ca}^{2+} and phosphate is PO43โˆ’\text{PO}_4^{3-}.

Solution

  1. 1
    Crisscross method: take the magnitude of each ion's charge and use it as the subscript for the other ion.
  2. 2
    Ca2+\text{Ca}^{2+} and PO43โˆ’\text{PO}_4^{3-}: the subscript for Ca becomes 3 (from the 3โˆ’3- charge) and the subscript for PO4\text{PO}_4 becomes 2 (from the 2+2+ charge).
  3. 3
    Formula: Ca3(PO4)2\text{Ca}_3(\text{PO}_4)_2. Verify: 3(+2)+2(โˆ’3)=+6โˆ’6=03(+2) + 2(-3) = +6 - 6 = 0. Neutral. Parentheses are needed around PO4\text{PO}_4 because its subscript is greater than 1.

Answer

Ca3(PO4)2\text{Ca}_3(\text{PO}_4)_2
The crisscross method works for any ionic compound. When polyatomic ions have a subscript greater than 1, enclose them in parentheses. Always verify that the total charges balance to zero.

About Formula Writing

The systematic process of combining element symbols and numerical subscripts to represent the exact composition of a chemical compound, ensuring that the total positive charge.

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